Catalytic, Enantioselective Synthesis of Allenyl Boronates
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Synthesis_of_Allenyl_Boronates/6042035
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资源简介:
A method
to achieve enantioselective 1,4-hydroboration of terminal
and internal enynes to access allenyl boronates under CuH catalysis
is described. The reaction typically proceeds in a highly stereoselective
manner and tolerates an array of synthetically useful functional groups.
The utility of the enantioenriched allenyl boronate products is demonstrated
through several representative downstream derivatizations.
创建时间:
2018-03-28



