Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph2PH to α,β-Unsaturated Imines
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Enaminophosphines_via_Palladacycle_Catalyzed_Addition_of_Ph_sub_2_sub_PH_to_Unsaturated_Imines/2495302
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A highly reactive, chemo- and enantioselective addition of diphenylphosphine to α,β-unsaturated imines catalyzed by a palladacycle has been developed, thus providing the access to a series of chiral tertiary enaminophosphines in high yields. A putative catalytic cycle has also been proposed.
创建时间:
2016-02-20



