Reactivity Studies of LAlH<sub>2</sub> (L = HC(CMeNAr)<sub>2</sub>, Ar = 2,6‑<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) with 2‑Aminobenzenethiol, 2‑Aminophenol, and 1,4-Dithiane-2,5-diol
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The reaction of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with 2-aminobenzenethiol, 2-aminophenol, and 1,4-dithiane-2,5-diol resulted in the compounds LAl[(μ-N)(μ-S)](o-C6H4) (2), LAl[(μ-O)(o-C6H4)(NH2)]2 (3), and LAl(μ-O)2(p-dithiane) (4), respectively. Compound 2 features an organic–inorganic hybrid containing an NAlSC2 five-membered ring, while compound 3 exhibits a C–O–Al–O–C chain structure. Compound 4 forms a basket-like molecule with the C4S2 unit as the bottom part and O2Al as the handle. Complexes 2, 3, and 4 were characterized by 1H NMR, elemental analysis, and single-crystal X-ray diffraction studies.
创建时间：
2012-09-10
