Synthesis and Characterization of Redox-Active Coordination Polymers Generated from Ferrocene-Containing Bridging Ligands
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Redox-Active_Coordination_Polymers_Generated_from_Ferrocene-Containing_Bridging_Ligands/3604836
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资源简介：
Coordination polymers showing redox activity have been constructed by using ferrocene-based bidentate ligands,
1,1‘-(4-dipyridinethio)ferrocene (1) and 1,1‘-(2-dipyridinethio)ferrocene (2). The ligand of 1 formed an AgI coordination
polymer, 1·AgPF6·(CH3CN)2 (3). This complex showed a 1-D double-chain structure, with a weak interchain Ag···Ag
interaction. Combination of 1 with M(hfac)2 (M = Mn, Cu, Zn) afforded 1-D chain complexes, 1·M(hfac)2 (M = Mn
(5), Cu (6), Zn (7)). The complex 2·CuPF6 (8) showed a 1-D twisted helix-like chain structure.
创建时间：
2016-08-17
