Rhodium(III)-Catalyzed Olefinic C–H Alkynylation of Acrylamides Using Tosyl-Imide as Directing Group
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https://figshare.com/articles/dataset/Rhodium_III_Catalyzed_Olefinic_C_H_Alkynylation_of_Acrylamides_Using_Tosyl_Imide_as_Directing_Group/2233174
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资源简介:
The Rh(III)-catalyzed C–H
alkynylation of acrylamide derivative
is realized using a hypervalent alkynyl iodine reagent. The use of
a weakly coordinating directing group proved to be of critical importance.
This reaction displays broad functional group tolerance and high efficiency,
which opens a new synthetic pathway to access functionalized 1,3-enyne
skeletons.
创建时间:
2016-02-16



