Mono(phosphine)–M (M–PR3; M = Rh and Ir) complexes selectively prepared by postsynthetic metalation of a porous triarylphosphine-based metal–organic framework (MOF) exhibited excellent activity in th
Diiodo Re(I) complexes [ReI2(NO)(PR3)2(L)] (3, L = H2O; 4 , L = H2; R = iPr a, Cy b) were prepared and found to exhibit in the presence of “hydrosilane/B(C6F5)3” co-catalytic systems excellent acti
A series of new pincer iron complexes with electron-donating phosphinite-iminopyridine (PNN) ligands has been prepared and characterized. These iron compounds are efficient and selective catalysts for
A series of carbene–diether ligands were prepared and the corresponding Ag salts used to prepare the complexes RuHCl(PPh3)2(Im(OR)2) (Im(OR)2 = C3H2(NCH2CH2OR)2; R = Me (4a), t-Bu (4b), tert-hexyl
16-Electron iridium complexes bearing a silyl-1,8-naphthyridine-based bidentate ligand (napySi), Ir(κ2Si,N-napySi)(H)(coe)X [X = Cl (1) and Me (2)], were synthesized and characterized. Single-crystal
