Herein, we demonstrate that the incorporation of an acidic hydrogen-bond-donating squaramide moiety into a porous UiO-67 metal–organic framework (MOF) derivative leads to dramatic acceleration of the
A series of carbene–diether ligands were prepared and the corresponding Ag salts used to prepare the complexes RuHCl(PPh3)2(Im(OR)2) (Im(OR)2 = C3H2(NCH2CH2OR)2; R = Me (4a), t-Bu (4b), tert-hexyl
Diiodo Re(I) complexes [ReI2(NO)(PR3)2(L)] (3, L = H2O; 4 , L = H2; R = iPr a, Cy b) were prepared and found to exhibit in the presence of “hydrosilane/B(C6F5)3” co-catalytic systems excellent acti
Heating of [(COD)M(κ2-3-PiPr2-2-NMe2-indene)]+X- (M = Rh or Ir; X = BF4, PF6; COD = η4-1,5-cyclooctadiene) in a mixture of water and THF (48 h, 60 °C) afforded the neutral (COD)M(κ2-P,O) complexes (M
Five-coordinated rhenium(I) hydride complexes of the type [Re(Br)(H)(NO)(PR3)2] (R = Cy 2a, iPr 2b) were prepared from [Re(Br)2(NO)(PR3)2(η2-H2)] (R = Cy 1a, iPr 1b) via deprotonation of the η2-H2 lig
