Copper–Organic Cationic Ring with an Inserted Arsenic–Vanadium Polyanionic Cluster for Efficient Catalytic CrVI Reduction Using Formic Acid
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Polyanionic cluster [β-As8V14O42(H2O)]4– is well embedded in a large porous eight-membered cationic ring of the copper ligand, giving a stable host–guest supramolecular system. The assembly exhibits an efficient heterogeneous catalytic performance for the reduction of CrVI using formic acid at ambient temperature.
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2016-02-14
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