Stepwise Assembly of Pd6(RuL3)8 Nanoscale Rhombododecahedral Metal–Organic Cages via Metalloligand Strategy for Guest Trapping and Protection
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Stepwise synthesis of nanosized Pd−Ru heteronuclear metal–organic cages from predesigned redox- and photo-active Ru(II)-metalloligand and naked Pd(II) ion is described. The resulting cage shows rhombododecahedral shape and contains a 5350 Å3 cavity and 12 open windows, facilitating effective trapping of both polar and nonpolar guest molecules. Protection of photosensitive guests against UV radiation is studied.
创建时间：
2016-02-17
