Structurally Reinforced Tetraazamacrocyclic Complexes
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https://figshare.com/articles/dataset/Structurally_Reinforced_Tetraazamacrocyclic_Complexes/3625680
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资源简介：
The reaction between alkyl or aryl aldehydes and macrocyclic ligands with pendant amine groups produced
imidazolidine-containing bi- or tricyclic ligands. The copper complexes of three of these ligands were structurally
characterized: [CuL3Cl]·3H2O (triclinic, P1̄, a = 10.041(2) Å, b = 10.172(1) Å, c = 11.202(1) Å, α =
92.07(1)°, β = 96.76(2)°, γ = 92.99(1)°, Z = 2), [Cu(H2L4)Cl]Cl·2H2O (monoclinic, P21/n, a = 15.159(5) Å,
b = 10.645(1) Å, c = 19.094(6) Å, β = 93.78(1)°, Z = 4), [CuL5]·2H2O·NaNO3 (monoclinic, P21/n, a =
10.649(8) Å, b = 7.261(2) Å, c = 15.25(1) Å, β = 94.77(4)°, Z = 2). The conformational rigidity and
stereochemical activity of these macrocycles and their complexes are discussed in comparison with close
analogues.
创建时间：
2016-08-18
