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PREPARATION PROCESS OF NEW-ENERGY BIOMASS MATERIAL FOR 3D PRINTING

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国家林业和草原科学数据中心2023-02-12 更新2024-03-07 收录
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The present invention provides a preparation process of a new-energy biomass material for 3D printing, which includes: mixing a cellulose raw material with a thermoplastic plastic powder in equal proportions to obtain a cellulose plastic powder, adding polyethylene glycol into the cellulose plastic powder for swelling for 1 hour at 120°C; then dispersing in a homogenizer for 10 minutes to obtain a polyethylene glycol dispersion liquid; washing away the polyethylene glycol in the polyethylene glycol dispersion liquid by using dichloromethane to obtain a dichloromethane suspension dispersion liquid; adding a coupling agent into the dichloromethane suspension dispersion liquid and magnetically stirring to obtain a surface-modified cellulose microfiber; adding the modified cellulose microfiber, a plasticizer and a flexibilizer into a PLA dichloromethane solution; stirring, recovering a dichloromethane solvent through a condensing unit, and removing the residual dichloromethane to obtain a cellulose microfiber/PLA composite material; and extruding the cellulose microfiber/PLA composite material with a linear extruder to obtain a cellulose-based 3D printing wire, thus realizing an effect of using cellulose and/or polylactic acid to prepare the 3D printing wire. 1/1 Si According to a functional requirement of a 3D printing wire, mixing a cellulose raw material with a thermoplastic plastic powder in equal proportions to obtain a cellulose plastic powder, then adding polyethylene glycol (PEG) into the cellulose plastic powder for swelling for 1 hour at 120°C S2 Mechanically extruding the swollen cellulose plastic powder, followed by dispersing in a homogenizer for 10 minutes to obtain a polyethylene glycol dispersion liquid containing a cellulose microfiber and a thermoplastic S3 Washing away the polyethylene glycol in the polyethylene glycol dispersion liquid containing the cellulose microfiber and the thermoplastic by using dichloromethane to obtain a dichloromethane suspension dispersion liquid containing the cellulose microfiber and the thermoplastic Adding a certain amount of a coupling agent into the dichloromethane suspension dispersion liquid containing the cellulose microfiber and the thermoplastic, and magnetically stirring and reacting for 30 minutes to obtain a surface-modified cellulose microfiber S5 Jointly adding the modified cellulose microfiber, a plasticizer and a flexibilizer into a PLA dichloromethane solution, wherein the PLA dichloromethane solution is a PLA dichloromethane solution with a certain concentration obtained by dissolving polylactic acid (PLA) in dichloromethane until the solution is completely transparent S6 Fully stirring and evenly mixing under a normal temperature, mechanically stirring at 60C, recovering a large amount of a dichloromethane solvent through a condensing unit, removing the residual small amount of dichloromethane through air drying to obtain a cellulose microfiber/PLA composite material S7 Extruding the cellulose microfiber/PLA composite material with a linear extruder to obtain a cellulose-based 3D printing wire, adding a part of the cellulose-based 3D printing wire into a grain cutting device, and cutting, rounding, drying and curing toobtain acellulose-based 3D printing particle End FIG. 1
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国家林业和草原科学数据中心
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2023-02-12
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