Complete and Partial 1,2-Additions across Transition Metal–Boron Double Bonds

The first 1,2-additions across a metal–boron double bond are reported, one a definitive chlorogallation of a FeB bond, the other a partial chlorogallation of a MoB bond that leads to a highly unusual, planar Mo–B–Ga–Cl rhombus. The two reactions occur with opposite regiochemistry, with the Ga atom bound to the Fe atom in the former and to both the Mo and B atoms in the latter. The bonding in the Mo adduct and the reasons for the differing regiochemistry of the reaction are explored computationally.