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A Mild Thermal and Acid-Catalyzed Rearrangement of <i>O</i>-Aryl Ethers into <i>ortho</i>-Hydroxy Arenes

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NIAID Data Ecosystem2026-03-06 收录
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An unusual rearrangement of an O-aryl ether to an ortho-hydroxyaryl system was discovered during our studies on the synthesis of diazonamide A. We discuss the exploration of this rearrangement under mild thermal and both Brønsted and Lewis acid-catalyzed conditions.

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2016-05-12
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