<i>trans</i>-[Os<sup>III</sup>(salen)(CN)<sub>2</sub>]<sup>−</sup>: A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials
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A novel dicyanoosmium(III) complex, trans-Ph4P[OsIII(salen)(CN)2]·CH2Cl2·H2O (1; Ph4P+ = tetraphenylphosphonium cation, salen2− = N,N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4)2 (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)]·CH3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)]·ClO4 (3).
创建时间：
2016-02-25
