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Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Trifluoromethyl_Substituted_Sulfonium_Ylide_Rh_Catalyzed_Carbenoid_Addition_to_Trifluoromethylthioether/2161249
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资源简介:
A highly efficient Rh-catalyzed carbenoid addition to trifluoro­methyl­thioether for the formation of trifluoromethyl-substituted sulfonium ylide is described. The trifluoro­methyl-substituted sulfonium ylide can act as an electrophilic trifluoro­methylation reagent, as demonstrated by trifluoro­methylation of β-ketoesters and aryl iodides.
创建时间:
2016-02-13
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