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Chromium-Mediated Synthesis of Polycyclic Aromatic Compounds from Halobiaryls

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Chromium_Mediated_Synthesis_of_Polycyclic_Aromatic_Compounds_from_Halobiaryls/3255550
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资源简介:
Reaction of 2,2‘-dihalobiphenyl with butyllithium followed by the addition of chromium(III) chloride and alkynes afforded the corresponding phenanthrene derivatives via formal [4 + 2] cycloaddition. A variety of alkynes could be used for this reaction, such as alkyl, aryl, silyl, and alkoxycarbonyl alkynes. Repetitive process of the reaction gave more extended polycyclic compounds such as benzo[g]chrysene and azacyclopentaphenalene derivatives.
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2016-05-05
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