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Anion Binding to Monotopic and Ditopic Macrocyclic Amides

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Anion_Binding_to_Monotopic_and_Ditopic_Macrocyclic_Amides/3069784
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Binding of fluoride anion as well as carboxylic acid tetraalkylammonium salts by macrocyclic compounds of different size was studied by NMR in DMSO-d6. It has been found that at least a 15-membered ring is necessary for successful recognition of fluoride. Larger macrocycles obtained in a [2 + 2] cyclization were shown to bind dicarboxylic acid salts. Effects of binding topicity are discussed.
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2016-03-01
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