Cationic Main-Group Metal Chalcogenide with a 1-D Polymeric Structure, [{In(dien)}₂(InTe₄)]·Cl

Coordination of unsaturated [In(amine)]3+ onto indium telluride structure, where the complex ion has higher positive charge, not only forms an organic−inorganic hybrid polymeric structure, but also offers an indium telluride with positive charge. Based on this strategy, cationic networks of metal chalcogenide may be expected.