Stepwise Cycloadditions of Mesoionic Systems: Thionation of Thioisomünchnones by Isothiocyanates
收藏NIAID Data Ecosystem2026-03-06 收录
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An unusual thionation strategy of mesoionic compounds with aryl isothiocyanates enables a facile synthesis of 1,3-thiazolium-4-thiolate systems. The mechanistic pathway of such a transformation most likely involves a stepwise 1,3-dipolar cycloaddition, which is supported by theoretical calculations performed with a two-layer hybrid method (B3LYP/6-31G(d):PM3).
创建时间：
2016-06-03
