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Three-Coordinate N-Heterocyclic Carbene Nickel Nitrosyl Complexes

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NIAID Data Ecosystem2026-03-06 收录
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The N-heterocyclic carbene IPr serves as a supporting ligand in a series of low-coordinate nickel nitrosyl complexes which display a range of nitrosyl bonding modes. Attempts to form a cationic two-coordinate nickel nitrosyl led to the three-coordinate {[IPr][IPr′]Ni(NO)}+[BArF4]−, in which one of the IPr ligands exhibits unusual C(5) coordination.

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2016-02-25
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