Isoreticular Metal–Organic Frameworks Pillared by Monovalent Anions
收藏NIAID Data Ecosystem2026-05-10 收录
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https://figshare.com/articles/dataset/Isoreticular_Metal_Organic_Frameworks_Pillared_by_Monovalent_Anions/30128094
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资源简介：
Three isoreticular anion pillared metal–organic
frameworks
were synthesized using CuX2 (X = BF4–, ClO4–, NO3–) salts and the 1,1′-(2-(trifluoromethyl)-1,4-phenylene)bis(1H-imidazole)
ligand (bibCF3). Single-crystal X-ray diffraction reveals
that these peculiar materials, of the general formula [Cu(bibCF3)2X]·X, feature bidentate monovalent anions
acting as pillars between square layers designed by metal ions and
organic linkers and extraframework anions located in the channel-like
pores. The materials display remarkable thermal and chemical stability
and promising CO2 adsorption performance, dependent on
the nature of the anion.
创建时间：
2025-09-15
