Carbene-Stabilized Beryllium Borohydride
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https://figshare.com/articles/dataset/Carbene_Stabilized_Beryllium_Borohydride/2512297
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资源简介：
The reaction of N-heterocyclic carbene, L:, with BeCl2 quantitatively yields L:BeCl2 1 (L:
= :C{N(2,6-Pri2C6H3)CH}2). The
carbene-stabilized beryllium borohydride monomer L:Be(BH4)2 2 is prepared by the reaction of 1 with LiBH4. Compound 3, prepared
by the reaction of 2 with Na2[Fe(CO)4]·dioxane, represents an unusual “dual reduction”
of the imidazole ring (i.e., hydroboration of the CC backbone
and hydrogenation of the C2 carbene center).
创建时间：
2012-06-20
