Carbene-Stabilized Beryllium Borohydride
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资源简介：
The reaction of N-heterocyclic carbene, L:, with BeCl2 quantitatively yields L:BeCl2 1 (L: = :C{N(2,6-Pri2C6H3)CH}2). The carbene-stabilized beryllium borohydride monomer L:Be(BH4)2 2 is prepared by the reaction of 1 with LiBH4. Compound 3, prepared by the reaction of 2 with Na2[Fe(CO)4]·dioxane, represents an unusual “dual reduction” of the imidazole ring (i.e., hydroboration of the CC backbone and hydrogenation of the C2 carbene center).
创建时间：
2012-06-20
