Enlarging the π System of Phosphorescent (C^C*) Cyclometalated Platinum(II) NHC Complexes

Cyclometalated (C^C*) platinum­(II) N-heterocyclic carbene (NHC) complexes are emerging as a new class of phosphorescent emitters for the application in organic light-emitting devices (OLEDs). We present the synthesis of six new complexes of this class to investigate the influence of extended π systems. Therefore, six different NHC ligands with a varying number of additional phenyl substituents were used in combination with the monoanionic acetylacetonate (acac) ligand to obtain complexes of the general formula [(NHC)­Pt­(II)­(acac)]. The complexes were fully characterized by standard techniques and advanced spectroscopic methods (195Pt NMR). For all complexes the solid-state structure determination revealed a square-planar coordination of the platinum atom. Absorption and emission spectra were measured in thin amorphous poly­(methyl methacrylate) films at room temperature. Four compounds emit in the blue-green region of the visible spectrum with quantum yields of up to 81%.