Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides
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A new regioselective synthetic methodology for benzo[b]phosphole derivatives has been developed. Thus, a range of functionalized benzo[b]phosphole oxides could be synthesized via Rh(III)-catalyzed C–H alkenylation of arylthiophosphinamides with alkynes followed by formal phospha-Friedel–Crafts cyclization.
创建时间：
2016-10-17
