Palladium-Catalyzed Coupling of Haloalkynes with Allyl Acetate: A Regio- and Stereoselective Synthesis of (Z)-β-Haloenol Acetates
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Coupling_of_Haloalkynes_with_Allyl_Acetate_A_Regio_and_Stereoselective_Synthesis_of_i_Z_i_Haloenol_Acetates/2625328
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A Pd-catalyzed coupling of haloalkynes with allyl acetate has been reported, providing a convenient method for the stereoselective synthesis of (Z)-β-haloenol acetates in good yields. The synthetic utility of this method is demonstrated by the formation of functionalized enol acetates via the Suzuki–Miyaura or Sonogashira coupling of the resulting (Z)-β-haloenol acetate products.
创建时间:
2016-02-23



