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Nestable Tetrakis(spiroborate) Nanocycles

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Figshare2016-02-13 更新2026-04-29 收录
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Multicomponent construction of the tetrakis­(spiroborate) anionic nanocycles was achieved by reacting bis­(dihydroxynaphthalene)­s with tetrahydroxyanthraquinone in the presence of boric acid in a self-organized manner. These nanocycles exhibited selective molecular recognition behavior toward cationic guests such as methyl viologen derivatives. Formation of a supramolecular ring@ring and a guest@ring@ring structure was observed by combining the anionic nanocycle and the vinylogous analog of cyclobis­(paraquat-p-phenylene).

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2016-02-13
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