Epoxidation of Bromoallenes Connects Red Algae Metabolites by an Intersecting Bromoallene Oxide - Favorskii Manifold
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https://figshare.com/articles/dataset/Epoxidation_of_Bromoallenes_Connects_Red_Algae_Metabolites_by_an_Intersecting_Bromoallene_Oxide_Favorskii_Manifold/785756/1
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资源简介：
DMDO epoxidation of bromoallenes gives directly a,b-unsaturated carboxylic acids under the reaction conditions. Calculated (wB97XD/6-311G(d,p)/SCRF=acetone) potential energy surfaces and 2H- and 13C-labeling experiments are consistent with bromoallene oxide intermediates which spontaneously rearrange via a bromocyclopropanone in an intersecting bromoallene oxide – Favorskii manifold.
提供机构：
figshare
创建时间：
2016-01-18
