Directed Amination of Aryl Methyl Ethers Mediated by Ti(NMe<sub>2</sub>)<sub>4</sub> at Room Temperature
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An efficient C–O amination of aryl methyl ethers has been achieved. This transformation proceeds via imine-directed Ti(IV)-mediated cross-coupling reactions between aryl methyl ethers and Ti(NR2)4 at room temperature, straightforwardly leading to a series of arylamines. This protocol features a wide substrate scope, exclusive regioselectivity, and mild reaction conditions.
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2016-02-13
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