A Ferrocenyldiphosphene−Platinum Complex: Structural Features and Theoretical Calculations
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The ligand exchange reaction of (E)-TbtPPFc (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Fc = ferrocenyl) and ethylenebis(triphenylphosphine)platinum(0) resulted in the formation of the corresponding η2-diphosphene−platinum complex in 82% yield. The molecular structure of the platinum complex was confirmed by spectroscopic and X-ray crystallographic analyses.
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2016-02-27
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