A Highly Regioselective Cyanothiolation of Alkynes via Oxidative Addition of Thiocyanates to Tetrakis(triphenylphosphine)palladium(0) Catalyst
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https://figshare.com/articles/dataset/A_Highly_Regioselective_Cyanothiolation_of_Alkynes_via_Oxidative_Addition_of_Thiocyanates_to_Tetrakis_triphenylphosphine_palladium_0_Catalyst/3070465
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资源简介：
Tetrakis(triphenylphosphine)palladium(0) catalyzes
the highly regioselective addition of phenyl thiocyanate (PhSCN)
to terminal alkynes, which attains the simultaneous introduction
of thio and cyano groups to the internal and terminal positions
of alkynes, respectively. This reaction may proceed via the
oxidative addition of PhSCN to Pd(PPh3)4, which forms Pd(SPh)(CN)(PPh3)2 as the key intermediate.
创建时间：
2016-03-01
