The Nucleophilicity of a Dialkylcarbene: Unusual Activation Parameters for Additions of Adamantanylidene to Simple Alkenes
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Computational and experimental results demonstrate that adamantanylidene (1) behaves as a highly reactive nucleophile toward common alkenes. It is the only known saturated nucleophilic carbene that lacks direct or vinylogous heteroatomic substitution. The activation energy and enthalpy for addition of 1 to methyl acrylate are the most negative values yet encountered in any carbene–alkene addition.
创建时间：
2016-02-17
