The First Spirobifluorenes Containing Two Binaphthyl Moieties
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https://figshare.com/articles/dataset/The_First_Spirobifluorenes_Containing_Two_Binaphthyl_Moieties/3355657
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资源简介:
The first spirobifluorenes comprising two
binaphthyl moieties with silicon or germanium at the
site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both
molecules have highly distorted structures, resulting in
a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature
dependency of the NMR spectra.
创建时间:
2003-12-22



