Achievement of Bulky Homochirality in Zeolitic Imidazolate-Related Frameworks
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https://figshare.com/articles/dataset/Achievement_of_Bulky_Homochirality_in_Zeolitic_Imidazolate_Related_Frameworks/2102503
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资源简介:
Before
this work, adding chiral C centers into zeolitic imidazolate frameworks
(ZIFs) has never been realized. Presented here are the first examples
on achieving bulky homochirality in ZIF systems, and three homochiral
zeolitic imidazolate-related frameworks with sodalite and dia topologies
are successfully synthesized by employing enantiopure imidazolate
derivatives. The results open a new blueprint on the synthetic design
of homochiral ZIFs for future applications.
创建时间:
2016-02-12



