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Achievement of Bulky Homochirality in Zeolitic Imidazolate-Related Frameworks

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Achievement_of_Bulky_Homochirality_in_Zeolitic_Imidazolate_Related_Frameworks/2102503
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资源简介:
Before this work, adding chiral C centers into zeolitic imidazolate frameworks (ZIFs) has never been realized. Presented here are the first examples on achieving bulky homochirality in ZIF systems, and three homochiral zeolitic imidazolate-related frameworks with sodalite and dia topologies are successfully synthesized by employing enantiopure imidazolate derivatives. The results open a new blueprint on the synthetic design of homochiral ZIFs for future applications.
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2016-02-12
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