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Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium

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NIAID Data Ecosystem2026-03-06 收录
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The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate a cis-aminopalladation mechanism.

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2016-05-06
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