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A Zwitterionic Palladium(II) η<sup>3</sup>-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand

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NIAID Data Ecosystem2026-03-06 收录
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A free phosphine/thioether/borane ligand (5) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd2(dba)3] gave a zwitterionic palladium(II) η3-boratoxypentadienyl complex with the empirical formula [Pd(dba)(5)].

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2016-05-05
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