Two Isomeric Magnesium Metal–Organic Frameworks with [24-MC-6] Metallacrown Cluster
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https://figshare.com/articles/dataset/Two_Isomeric_Magnesium_Metal_Organic_Frameworks_with_24_MC_6_Metallacrown_Cluster/2419726
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资源简介：
Two
novel Mg-based metal–organic framework isomers with
the formula [Mg2(HCO2)2(NH2-BDC)(DMF)2]n (NH2-BDC = 2-amino-1,4-benzenedicarboxylate) have been synthesized based
on a 6-connected [24-MC-6] metallacrown secondary building unit (SBU),
which display a two-dimensional (2D) 36 net (1) and three-dimensional primitive rhombohedral net (2) derived from a different extended orientation of SBU, respectively.
The 2D framework of 1 exhibits relevant thermal stability,
solvents stability, high CO2 adsorption, and strong luminescent
properties.
创建时间：
2013-05-01
