Formation of a Heterometallic Al<sup>III</sup>/Sm<sup>III</sup> Complex Involving a Novel [EtAl(2-py)<sub>2</sub>O]<sup>2–</sup> Ligand (2-py = 2‑Pyridyl)
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Controlled O2 oxidation of the Sm(II) sandwich compound [{EtAl(2-py)3}2Sm] (1a) gives the Sm(III)/Al(III) compound [{EtAl(2-py)3}{EtAl(2-py)2O}Sm]2 (2), containing the novel multifunctional dianionic ligand [EtAl(2-py)2O]2–. The formation of an O-bridged Al-O-Sm arrangement in the structure of 2 is potentially relevant to the catalytic epoxidation of styrene with dry air using heterobimetallic sandwich compounds like 1a.
创建时间：
2014-12-22
