Rhodium(III)-Catalyzed Directed ortho-C–H Bond Functionalization of Aromatic Ketazines via C–S and C–C Coupling
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https://figshare.com/articles/dataset/Rhodium_III_Catalyzed_Directed_i_ortho_i_C_H_Bond_Functionalization_of_Aromatic_Ketazines_via_C_S_and_C_C_Coupling/2111656
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Described herein is a convenient and efficient method for sulfuration and olefination of aromatic ketazines via rhodium-catalyzed oxidative C–H bond activation. A range of substituted substrates are supported, and a possible mechanism is proposed according to experimental results of kinetic isotopic effect, reversibility studies, and catalysis of rhodacycle intermediate c1.
创建时间：
2016-02-12
