Rhodium(III)-Catalyzed Directed ortho-C–H Bond Functionalization of Aromatic Ketazines via C–S and C–C Coupling
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Described herein is a convenient and efficient method for sulfuration and olefination of aromatic ketazines via rhodium-catalyzed oxidative C–H bond activation. A range of substituted substrates are supported, and a possible mechanism is proposed according to experimental results of kinetic isotopic effect, reversibility studies, and catalysis of rhodacycle intermediate c1.
创建时间：
2016-02-12
