A Bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me3Si(CNAr)SiMe2(CNAr)SiMe3 (Ar = 2,6-xylyl), as a New β-Diimine Ligand‖

Figshare2007-11-19 更新2026-04-28 收录

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https://figshare.com/articles/dataset/A_Bis-_C_trimethylsilyl_-_i_N_i_-arylimino_dimethylsilane_Me_sub_3_sub_Si_C_NAr_SiMe_sub_2_sub_C_NAr_SiMe_sub_3_sub_Ar_2_6-xylyl_as_a_New_-Diimine_Ligand_sup_sup_/12078561

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A cobalt complex having bis-[C(trimethylsilyl)-N-arylimino]dimethylsilane, Me3Si(CNAr)SiMe2(CNAr)SiMe3 (Ar = 2,6-xylyl), as a new β-diimine ligand was synthesized, and its structure was compared with those of α- and β-diimine cobalt complexes. Ethylene polymerization catalyzed by these cobalt complexes and their in situ generated nickel homologues was investigated.

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2007-11-19