First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes
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https://figshare.com/articles/dataset/First_Isolation_and_Structural_Characterization_of_Triarylaluminum_Water_and_Methanol_Complexes/3774456
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资源简介:
The structurally characterized (C6F5)3Al·OH2
(1) and (C6F5)3Al·OHCH3 (2) exhibit medium-strong
intermolecular and weak intramolecular O−H···FC
hydrogen bonds in the solid state. Both complexes have
substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong
activation of the weak Brønsted acid H2O by Al(C6F5)3.
创建时间:
2016-08-26



