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First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes

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https://figshare.com/articles/dataset/First_Isolation_and_Structural_Characterization_of_Triarylaluminum_Water_and_Methanol_Complexes/3774456
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The structurally characterized (C6F5)3Al·OH2 (1) and (C6F5)3Al·OHCH3 (2) exhibit medium-strong intermolecular and weak intramolecular O−H···FC hydrogen bonds in the solid state. Both complexes have substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong activation of the weak Brønsted acid H2O by Al(C6F5)3.
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2016-08-26
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