Development of an Approach to the Synthesis of the ABC Ring System of Hemibrevetoxin B
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https://figshare.com/articles/dataset/Development_of_an_Approach_to_the_Synthesis_of_the_ABC_Ring_System_of_Hemibrevetoxin_B/3059512
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资源简介：
An efficient approach for the synthesis of a model of the ABC ring system of Hemibrevetoxin B is described. Key features include a ring
expansion to yield the ring C oxepane, the reduction of a 2-furyl ketone with high levels of 1,3-stereocontrol, and an Achmatowicz oxidative
ring expansion to yield the ring A tetrahydropyran. All seven stereogenic centers present in the model compound were controlled with high
levels (>98:<2) of diastereoselectivity.
创建时间：
2016-02-29
