Transition-Metal-Free Addition Reaction for the Synthesis of 3‑(Aminobenzylidene/aminoalkylidene)indolin-2-ones and Its Synthetic Applications
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https://figshare.com/articles/dataset/Transition-Metal-Free_Addition_Reaction_for_the_Synthesis_of_3_Aminobenzylidene_aminoalkylidene_indolin-2-ones_and_Its_Synthetic_Applications/9968177
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资源简介:
A novel
and efficient transition-metal-free approach for the exclusive
synthesis of Z-3-(aminobenzylidene/aminoalkylidene)indolin-2-ones
in high yield from 2-oxindole and aryl/alkyl nitrile in the presence
of LiOtBu and 2,2′-bipyridine system is described.
In addition, we disclosed a new approach towards the metal-free fluorination
using selectfluor and the CC bond cleavage using CuI and environmentally
benign O2.
创建时间:
2019-09-26



