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Direct Synthesis of Fluorescent 1,3a,6a-Triazapentalene Derivatives via Click–Cyclization–Aromatization Cascade Reaction

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_Synthesis_of_Fluorescent_1_3a_6a_Triazapentalene_Derivatives_via_Click_Cyclization_Aromatization_Cascade_Reaction/2626786
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An efficient and versatile method was established for the preparation of 1,3a,6a-triazapentalenes. The 1,3a,6a-triazapentalene skeleton without an additional fused ring system was discovered to be a compact and highly fluorescent chromophore, which exhibited various interesting fluorescent properties such as a noteworthy correlation of luminescent wavelength with the Hammett σp value and a strongly positive solvatofluorochromism.
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2016-02-23
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