Cerium(IV) Tellurite Halides [Ce<sub>2</sub>Te<sub>7</sub>O<sub>17</sub>]X<sub>2</sub> (X = Cl<sup>–</sup> or Br<sup>–</sup>): The First Cerium-Containing Cationic Frameworks
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Two isotypic cerium tellurite halides with the formulas [Ce2Te7O17]Cl2 and [Ce2Te7O17]Br2 have been synthesized hydrothermally via the reactions of CeCl3 and CeBr3 with TeO2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te7O176– building unit, forming an unusual hexagonal-bipyramidal environment around CeIV.
创建时间：
2012-10-01
