Cu(OTf)2‑Catalyzed Selective Arene C–H Bond Hydroxylation and Nitration with KNO2 as an Ambident O- and N‑Nucleophile via a Cu(II)–Cu(III)–Cu(I) Mechanism

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数据链接：

https://figshare.com/articles/dataset/Cu_OTf_sub_2_sub_Catalyzed_Selective_Arene_C_H_Bond_Hydroxylation_and_Nitration_with_KNO_sub_2_sub_as_an_Ambident_i_O_i_and_i_N_i_Nucleophile_via_a_Cu_II_Cu_III_Cu_I_Mechanism/2391553 数据链接链接失效反馈

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资源简介：

Cu(OTf)2-catalyzed selective arene C–H bond hydroxylation and nitration reactions of azacalix[1]arene[3]pyridines were achieved using KNO2 as an ambident O- and N-nucleophile under very mild aerobic conditions to yield functionalized azacalixaromatics. The reaction, which selectivity between hydroxylation and nitration was modulated by the reaction medium employed, proceeded through a Cu(II)–Cu(III)–Cu(I) mechanism.

创建时间：

2016-02-19

Cu(OTf)<sub>2</sub>‑Catalyzed Selective Arene C–H Bond Hydroxylation and Nitration with KNO<sub>2</sub> as an Ambident <i>O</i>- and <i>N</i>‑Nucleophile via a Cu(II)–Cu(III)–Cu(I) Mechanism

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