A New Synthetic Route to High-Valent Half-Sandwich Group 4 Metallacarborane Alkyls. Synthesis and Structural Characterization of [η<sup>1</sup>:η<sup>6</sup>-(Me<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>)C<sub>2</sub>B<sub>10</sub>H<sub>11</sub>]Hf(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>2</sub>
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数据链接：
https://figshare.com/articles/dataset/A_New_Synthetic_Route_to_High_Valent_Half_Sandwich_Group_4_Metallacarborane_Alkyls_Synthesis_and_Structural_Characterization_of_sup_1_sup_sup_6_sup_Me_sub_2_sub_NCH_sub_2_sub_CH_sub_2_sub_C_sub_2_sub_B_sub_10_sub_H_sub_11_sub_Hf_CH_sub_2_sub_SiMe_sub_3_su/3281503数据链接链接失效反馈
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资源简介：
A half-sandwich group 4 metallacarborane alkyl was prepared and structurally characterized for the first time via an alkane elimination reaction of Hf(CH2SiMe3)4 with the zwitterionic salt Me2NHCH2CH2C2B10H12. This method avoids using the strong reducing agents [nido-R2C2B10H10]M2 (M = group 1 metal) as starting materials, which allows the synthesis of high-valent group 4 metallacarboranes of the C2B10 system.
创建时间：
2016-05-06
