Reductive Homocondensation of Benzylidene- and Alkylidenepyruvate Esters by a P(NMe2)3‑Mediated Tandem Reaction
收藏Figshare2016-02-19 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Reductive_Homocondensation_of_Benzylidene_and_Alkylidenepyruvate_Esters_by_a_P_NMe_sub_2_sub_sub_3_sub_Mediated_Tandem_Reaction/2422750
下载链接
链接失效反馈官方服务：
资源简介：
A reductive homocondensation of E-benzylidenepyruvate esters mediated by P(NMe2)3 is described. The transformation, initiated by the Kukhtin–Ramirez addition of the phosphorus reagent to the vinyl-substituted α-dicarbonyl substrate, proceeds via a resonance delocalized oxyphosphonium dienolate intermediate to provide access to diverse oxygenated heterocycles as a function of the substituent.
创建时间：
2016-02-19
