A Rare η<sup>3</sup> Binding Mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes
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A rare η3 binding mode of aryloxides was obtained in the reaction of BINOL and [Cp*IrCl2]2. Interconversions between and η1 and η3 modes of aryloxides were observed by VT NMR spectroscopy, and the activation barrier was measured. The preference of this binding mode as a function of phenols was discussed.
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2008-12-22
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