Unprecedented Low Cu−N(azide)−Cu Angles in End-On Double Azido Bridged Copper(II) Complex
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https://figshare.com/articles/dataset/Unprecedented_Low_Cu_N_azide_Cu_Angles_in_End_On_Double_Azido_Bridged_Copper_II_Complex/3350617
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资源简介：
A rare asymmetric end-on double azido-bridged copper(II) complex
has been synthesized and characterized structurally and magnetically. The Cu−N(azide)−Cu angle in this complex is calculated to
be 89.1°. This is unusually low in comparison to the same angle
in other end-on azido-bridged binuclear complexes reported so
far. Though a strong ferromagnetic interaction between the metal
centers is expected in the complex, the coupling has actually been
found to be antiferromagnetic, instead.
创建时间：
2016-05-07
